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1,4 butynediol ibicuruzwa bisumba byose
CAS: 110-65-6
Imiterere yimiti ya butynediol: kirisiti yera ya orthorhombic.Gushonga ingingo 58 ℃, ingingo itetse 238 ℃, 145 ℃ (2KPa), flash point 152 ℃, indangagaciro yo kwanga 1.450.Gushonga mumazi, umuti wa aside, Ethanol na acetone, gushonga gake muri chloroform, kudashonga muri benzene na ether.
Imikoreshereze: butynediol irashobora gukoreshwa mugukora butene glycol, butynediol, n-butanol, dihydrofuran, tetrahydrofuran γ- Urukurikirane rwibicuruzwa byingenzi kama nka butyrolactone na pyrrolidone birashobora gukoreshwa mugukora plastike yubukorikori, fibre synthique (nylon-4), uruhu rwubukorikori, ubuvuzi, imiti yica udukoko, imiti (N-methyl pyrrolidone) hamwe nuburinzi.Butynediol ubwayo nigisubizo cyiza kandi ikoreshwa nkurumuri mumashanyarazi.
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Umuhondo wijimye wijimye cyane 1,4-butynediol
1,4-butynediol ikomeye, imiti ya C4H6O2, kirisiti yera ya orthorhombic.Gushonga mumazi, aside, Ethanol na acetone, kudashonga muri benzene na ether.Irashobora kurakaza ururenda, uruhu hamwe nubuhumekero bwo hejuru bwamaso.Mu nganda, 1,4-butynediol ikomeye itegurwa cyane cyane nuburyo bwa Reppe, igatangizwa na butynediol y'umuringa cyangwa umuringa wa bismuth, kandi igategurwa na reaction ya acetylene na formaldehyde munsi yigitutu (1 ~ 20 bar) no gushyushya (110 ~ 112 ° C) .Butynediol itaboneka iboneka binyuze mubitekerezo, kandi ibicuruzwa byarangiye biboneka binyuze mubitekerezo no gutunganya.
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3-chloropropyne idafite ibara ryinshi uburozi bwaka umuriro
3-chloropropyne ni ifumbire mvaruganda hamwe na formulaire ch ≡ cch2cl.Ibigaragara ni ibara ritagira ibara ryaka.Gushonga ingingo -78 ℃, ingingo itetse 57 ℃ (65 ℃), ubucucike bugereranije 1.0297, igipimo cyangirika 1.4320.Flash point 32.2-35 ℃, hafi yo kudashonga mumazi na glycerol, ntibishobora gukoreshwa na benzene, tetrachloride ya karubone, Ethanol, Ethylene glycol, ether na acetate ya Ethyl.Biboneka mugukora alcool ya propargyl hamwe na fosifore trichloride.Byakoreshejwe nkigihe gito muri synthesis organique.
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Uburozi bukabije bwamazi arenze ibicuruzwa propargyl alcoho
Amazi adafite ibara, ahindagurika afite impumuro mbi.Biroroshye guhinduka umuhondo iyo ushyizwe mugihe kirekire, cyane cyane iyo uhuye numucyo.Ntibishobora gukoreshwa namazi, benzene, chloroform, 1,2-dichloroethane, ether, Ethanol, acetone, dioxane, tetrahydrofuran na pyridine, bigashonga igice muri tetrachloride ya karubone, ariko ntibishobora gushonga muri hydrocarbone ya alifatique.
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Inzira yo gukora inzoga ya propargyl no gusesengura isoko
Inzoga ya Propargyl (PA), imiti izwi nka 2-propargyl alcool-1-ol, ni amazi atagira ibara, ahindagurika cyane kandi afite impumuro nziza yamababi.Ubucucike ni 0,9485g / cm3, aho gushonga: -50 ℃, aho batetse: 115 ℃, flash point: 36 ℃, gutwikwa, guturika: gushonga mumazi, chloroform, dichloroethane, methanol, etanol, etil ether, dioxane, tetrahydrofuran, pyridine, gushonga gato muri karubone tetrachloride, idashobora gushonga muri hydrocarubone ya alifatique.Inzoga ya Propargyl ni ibikoresho byingenzi bya shimi, bikoreshwa cyane mubuvuzi, inganda zikora imiti, amashanyarazi, imiti yica udukoko, ibyuma, peteroli nizindi nzego.
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Gukoresha butanediol mu kwisiga
Butanediol, cyane cyane acetylene na formaldehyde nkibikoresho fatizo.Ikoreshwa nk'iyagura urunigi mu gukora polybutylene terephthalate na polyurethane, kandi nk'ibikoresho by'ibanze bya tetrahydrofuran, γ-butyrolactone, ubuvuzi na synthesis.Kuberako polybutylene terephthalate ari ubwoko bwa polyester ifite imitungo myiza, ibyifuzo bya plastiki yubuhanga biriyongera vuba.
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Imiti ya laboratoire ifite ubumara bukabije - inzoga ya propargyl
Inzoga ya Propargyl, amata ya molekuline C3H4O, uburemere bwa molekile 56. Amazi adafite amabara meza, ahindagurika afite impumuro mbi, uburozi, kurakara cyane kuruhu n'amaso.Hagati mungingo ngengabihe.Ahanini ikoreshwa muguhuza imiti ya antibacterial na anti-inflammatory sulfadiazine;Nyuma ya hydrogène igice, inzoga ya propylene irashobora kubyara resin, hanyuma nyuma ya hydrogenation yuzuye, n-propanol irashobora gukoreshwa nkibikoresho fatizo byimiti igabanya ubukana bwitwa ethambutol, nibindi bicuruzwa bivura imiti na farumasi.Irashobora kubuza aside ibyuma, umuringa na nikel hamwe nibindi byuma byangirika, bikoreshwa mugukuraho ingese.Byakoreshejwe cyane mugukuramo amavuta.Irashobora kandi gukoreshwa nka solvent, stabilisateur ya hydrocarbone ya chlorine, ibyatsi byica udukoko.Irashobora gukoreshwa mugukora acide acrylic, acrolein, 2-aminopyrimidine, γ-picauline, vitamine A, stabilisateur, inhibitori ya ruswa nibindi.
Andi mazina: inzoga ya propargyl, 2-propargyl - 1-inzoga, inzoga 2-propargyl, inzoga ya propargyl acetylene methanol.
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Propargyl izahindura polymerize kandi iturike
Inzira yambere ishingiye kuri alcool ya propargyl nkibishishwa, KOH nkibishingwe, gushyushya reaction kugirango ubone intego.Igisubizo kidafite imiterere yo kugabanuka kizaba umwanda muke, reaction irasukuye.
Urebye ibishobora guterwa na polymerisime no guturika guturika kwa alkynes, Laboratwari ya Hazard Evaluation ya Amgen (HEL) yinjiye kugira ngo isuzume umutekano kandi ifashe mu buryo bunoze mbere yo gupima litiro 2 za reaction.
Ikizamini cya DSC cyerekana ko reaction itangira kubora kuri 100 ° C ikarekura ingufu za 3667 J / g, mugihe inzoga ya propargyl na KOH hamwe, nubwo ingufu zigabanuka zikagera kuri 2433 J / g, ariko ubushyuhe bwo kubora nabwo bukamanuka kuri 85 ° C, kandi ubushyuhe bwibikorwa buri hafi ya 60 ° C, ibyago byumutekano ni byinshi.
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1,4-butanediol (BDO) no gutegura ibinyabuzima byangiza PBAT
1, 4-butanediol (BDO);PBAT ni plastiki ya termoplastique ya biodegradable plastike, ikaba ikora kopolymer ya butanediol adipate na butanediol terephthalate.Ifite ibiranga PBA (polyadipate-1, 4-butanediol ester diol) na PBT (polybutanediol terephthalate).Ifite ihindagurika ryiza no kurambura kuruhuka, kimwe no kurwanya ubushyuhe bwiza no gukora ingaruka.Byongeye kandi, ifite ibinyabuzima byiza cyane kandi ni kimwe mu bikoresho bizwi cyane mu binyabuzima mu bushakashatsi bwa plastiki y’ibinyabuzima ndetse no gukoresha neza isoko.
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Umusaruro wa 1, 4-butanediol (BDO) hakoreshejwe uburyo bwa anhydride ya kigabo
Hariho inzira ebyiri zingenzi zo gukora BDO na anhydride ya kigabo.Imwe muriyo ni inzira ya hydrogenation itaziguye ya anhydride yumugabo yakozwe na Mitsubishi Petrochemical na Mitsubishi Chemical mu Buyapani mu myaka ya za 70, irangwa no gukora icyarimwe icyarimwe cya BDO, THF na GBL mugikorwa cya hydrogenation ya anhydride yumugabo.Ibicuruzwa byahimbwe bitandukanye birashobora kuboneka muguhindura imikorere.Ibindi ni inzira ya gaz esterification hydrogenation ya anhydride yumugabo yakozwe na Sosiyete ya UCC hamwe na Davey Process Technology Company mu Bwongereza, ikaba yaratejwe imbere n’ikoranabuhanga rito rya karubone.Muri 1988, kongera gusuzuma isuzuma ryibikorwa byarangiye kandi hasabwa igishushanyo mbonera.Mu 1989, IKORANABUHANGA ryimuriwe muri DongSANG CHEMICAL COMPANY YO MURI Koreya NA DONGGU CHIMICAL YUbuyapani KUBAKA 20.000-TON / umwaka 1, 4-BUtanEDIOL INGANDA Y’inganda.
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1, 4-butanediol
1, 4-butanediol
Alias: 1, 4-dihydroxybutane.
Amagambo ahinnye: BDO, BD, BG.
Izina ry'icyongereza: 1, 4-Butanediol;1, 4 - butylene glycol;1, 4 - dihydroxybutane.
Inzira ya molekile ni C4H10O2 naho uburemere bwa molekile ni 90.12.Numero ya CAS ni 110-63-4, naho EINECS nimero 203-785-6.
Inzira yuburyo: HOCH2CH2CH2CH2OH.
Ibicuruzwa
Inzobere mu gukora inzoga za propargyl, 1,4 butynediol na 3-chloropropyne
